extraction and perconcentrationlead (ii) using octadecyl bonded silica cartridge and determination by faas

نویسندگان

moghimi a. shaabanzadeh m.

چکیده

a simple method has been developed for the preconcentration of lead (ii) based on the adsorption of its 1-(2-pyridyl azo)2-naphtol (pan) complex on aoctadecyl bonded silica cartridges. the influence of acidity, eluting agents, stability of the column, sample volume and interfering ions has been investigated in detail. the adsorbed complex could be eluted using environmentally benign hno34m and the concentration of lead (ii) was determined flame atomic absorption spectrometry. a detection limit of 50 µgl −1 could be achieved and the developed procedure was successfully applied for the determination of lead (ii) in tap water and waste water samples.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

extraction and determination of trace copper (ii) using octadecyl silica membrane disks modified 1-(2-pyridyl azo) 2-naphtol(pan) in water samples and paraffin-embedded tissues from liver loggerhead turtles specimens by faas

a simple and reproducible method for the rapid extraction and determination of trace amounts of copper(ii) ions using octadecyl-bonded silica membrane disks modified by 1-(2-pyridyl azo)2-naphtol(pan) and atomic absorption spectrometry was presented. the method was based on complex formation on the surface of the envi-18 disk tm disks followed by stripping of the retained species by minimum amo...

متن کامل

Determination of inorganic anions by capillary ion-exchange chromatography using polyethylenimine-coated octadecyl-bonded phases.

The utility of a cationic polymer polyethylenimines (PEI) for coating some commercially available silica-based stationary phases packed in capillaries of 0.32 mm i.d. and 10 cm long was studied for the separation and direct UV detection of inorganic anions (iodate, bromate, nitrite, bromide, and nitrate ions). With a super-endcapped octadecylated silica stationary phase, which yielded the best...

متن کامل

Extraction of Co(II) by Isocyanate Treated Graphite Oxides (iGOs) Adsorbed on Surfactant Coated C18 Before Determination by FAAS

A simple, highly sensitive, accurate and selective method for determination of trace amounts of Co(II) in water samples is presented. Isocyanate treated graphite oxides (iGOs) solid phase extraction adsorbent was synthesized by covalently isocyanate onto the surfaces of graphite oxides. The stability of a chemically (iGOs) especially in concentrated hydrochloric acid which was then used as a re...

متن کامل

Extraction of Co(II) by Isocyanate Treated Graphite Oxides (iGOs) Adsorbed on Surfactant Coated C18 Before Determination by FAAS

A simple, highly sensitive, accurate and selective method for determination of trace amounts of Co(II) in water samples is presented. Isocyanate treated graphite oxides (iGOs) solid phase extraction adsorbent was synthesized by covalently isocyanate onto the surfaces of graphite oxides. The stability of a chemically (iGOs) especially in concentrated hydrochloric acid which was then used as a re...

متن کامل

Preconcentration of Cadmium in Environmental Samples by Cloud Point Extraction and Determination by FAAS

Cloud point extraction (CPE) has been used for the preconcentration of cadmium, after the formation of a complex with 1, 5-bis(di-2-pyridylmethylene) thiocarbonohydrazide (DPTH), and further determination by flame atomic absorption spectrometry (FAAS) using Triton X-114 as surfactant. The main factors affecting the CPE, such as concentration of Triton X-114 and DPTH, pH, equilibration temperatu...

متن کامل

Evaluation of Factors Inf luencing Recovery of Herbicide 2,4-D from Drinking Water

Many modern analytical methods deal with the trace-level determination of compounds of interest in highly complex environmental samples by means of chromatographic techniques. The introduction of a “clean” sample into an analytical instrument can make analyses easier and prolongs the equipment life. The use of solid-phase extraction (SPE) has grown and is a fertile technique of sample prepa...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید


عنوان ژورنال:
journal of chemical health risks

جلد ۱، شماره ۲، صفحات ۰-۰

کلمات کلیدی
[ ' l e a d ( i i ) ' , ' p e r c o n c e n t r a t i o n ' , ' o c t a d e c y l b o n d e d s i l i c a c a r t r i d g e s ' , 1 , ' ( 2 ' , ' p y r i d y l a z o ) 2 ' , ' n a p h t o l ( p a n ) ' ]

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023